ENANTIOSELECTIVE SYNTHESIS OF MONOCERIN AND FUSARENTIN ETHERS - ANTIFUNGAL AND INSECTICIDAL FUNGAL METABOLITES

被引：31

作者：

DILLON, MP ^{[1
]}

SIMPSON, TJ ^{[1
]}

SWEENEY, JB ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,CANTOCKS CLOSE,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 49期

关键词：

ANTIFUNGAL; INSECTICIDAL; FUNGAL METABOLITES; BIOMIMETIC; BENZYLIC ANION;

D O I：

10.1016/S0040-4039(00)60826-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Fusarentin 4,5-dimethyl ether (4) is synthesized via condensation of the benzylic anion of ethyl 3,4,5-trimethoxy-6-methylbenzoate (7) with (S)-3-tetrahydropyranyloxyhexanal (8); subsequent biomimetic cyclisation of (4) gives monocerin (1).

引用

页码：7569 / 7572

页数：4

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