A STUDY OF EFFECT OF TEMPERATURE ON THE INFLUENCE OF MEDIUM ON THE REACTION OF TRIETHYLAMINE WITH ETHYL IODIDE

被引：7

作者：

BEKAREK, V

NEVECNA, T

机构：

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1991年 / 56卷 / 04期

关键词：

D O I：

10.1135/cccc19910874

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rate constants of the reaction of triethylamine with ethyl iodide have been measured in 15 solvents at the temperatures of 293, 313, 333 and 373 K. The solvent characteristics by Kamlet and Taft and those by Pytela have been found to be excellently applicable to evaluation of influence of medium on this reaction at all the temperatures mentioned. However, these methods give different results with regard to the proton-donor effects of solvents on the reaction.

引用

页码：874 / 879

页数：6

共 15 条

[1] QUANTITATIVE STUDY OF SOLVENT EFFECTS ON MENSHUTKIN REACTION BETWEEN 1,4-DIAZABICYCLO[2,2,2]OCTANE AND (2-CHLOROETHYL)BENZENE, (2-BROMOETHYL)BENZENE, AND (2-IODOETHYL)BENZENE [J].