MODELING SEMICONTINUOUS EMULSION TERPOLYMERIZATION

被引：40

作者：

URRETABIZKAIA, A ^{[1
]}

ARZAMENDI, G ^{[1
]}

ASUA, JM ^{[1
]}

机构：

[1] UNIV BASQUE COUNTRY, FAC CIENCIAS QUIM,DEPT QUIM APLICADA, INGN QUIM GRP,APDO 1072, E-20080 SAN SEBASTIAN, SPAIN

来源：

CHEMICAL ENGINEERING SCIENCE | 1992年 / 47卷 / 9-11期

关键词：

D O I：

10.1016/0009-2509(92)87096-9

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A mathematical model for the emulsion terpolymerization process was developed. The outputs of the model are the time evolution of the number of polymer particles, conversions of the monomers, latex solids content and terpolymer composition. The model was checked during the seeded semicontinuous emulsion terpolymerization of methyl methacrylate, butyl acrylate and vinyl acetate carried out using high solids content latexes. The parameters of the model were estimated using all the experimental results by means of a direct search algorithm. An excellent fitting of the experimental data was achieved.

引用

页码：2579 / 2584

页数：6

共 23 条

[1] OPTIMAL MONOMER ADDITION POLICIES FOR COMPOSITION CONTROL OF EMULSION TERPOLYMERS [J].