OPTICAL CO DETECTION BY USE OF CUO/AU COMPOSITE FILMS

被引:45
作者
ANDO, M [1 ]
KOBAYASHI, T [1 ]
HARUTA, M [1 ]
机构
[1] AIST, OSAKA NAT RES INST, IKEDA, OSAKA 563, JAPAN
关键词
CARBON MONOXIDE SENSORS; COPPER OXIDE; GOLD; OPTICAL SENSORS;
D O I
10.1016/0925-4005(95)85187-9
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Composite films consisting of a thin CuO layer and ultrafine Au particles have been found to be usable for the optical detection of CO in air. The optical absorption of CuO/Au composite films increases due to CO and recovers reversibly in air free of CO. The largest absorbance change due to CO is in the 700-800 nm wavelength region, with the absorbance change enhanced by increasing temperature or increasing CO concentration. We assume that the absorbance change of the CuO/Au film occurs due to the change in the electronic structure of the ultrafine Au particles as a result of their interactions with atmospheric gas.
引用
收藏
页码:851 / 853
页数:3
相关论文
共 8 条
[1]   ENHANCEMENT IN THE OPTICAL CO SENSITIVITY OF NIO FILM BY THE DEPOSITION OF ULTRAFINE GOLD PARTICLES [J].
ANDO, M ;
KOBAYASHI, T ;
HARUTA, M .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1994, 90 (07) :1011-1013
[2]  
ANDO M, 1993, 183RD P S CHEM SENS, P690
[3]  
Eguchi K., 1992, GAS SENSORS, P307
[4]   ENHANCING EFFECT OF GOLD DEPOSITION IN THE OPTICAL-DETECTION OF REDUCING GASES IN AIR BY METAL-OXIDE THIN-FILMS [J].
KOBAYASHI, T ;
HARUTA, M ;
ANDO, M .
SENSORS AND ACTUATORS B-CHEMICAL, 1993, 14 (1-3) :545-546
[5]  
KOBAYASHI T, 1990, 3RD P INT M CHEM SEN, P318
[6]  
NAGASE K, 1993, 183RD M EL SOC HON, P2092
[7]  
Turkevich J., 1985, GOLD BULL, V18, P125, DOI [10.1007/BF03214694, DOI 10.1007/BF03214694]
[8]   GAS-SENSITIVE OPTICAL-ABSORPTION OF ULTRAFINE SILVER PARTICLES DISPERSED IN A POROUS SILICA FILM [J].
YANASE, A ;
KOMIYAMA, H ;
TANAKA, K .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1988, 27 (02) :L164-L166