ISOLATION AND VIS-ABSORPTION SPECTRUM OF TRANS-[NI(OH2)(2)(CYCLAM)]CL-2-CENTER-DOT-4H(2)O

被引：66

作者：

MOCHIZUKI, K

KONDO, T

机构：

[1] Department of Chemistry, Yokohama City University

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 25期

关键词：

D O I：

10.1021/ic00129a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The trans-diaqua cyclam-Ni(II) complex was isolated as trans-[Ni(OH2)(2)(cyclam)]Cl-2 . 4H(2)O, which was confirmed by X-ray crystallography ([Ni(OH2)(2)(C10H24N4)]Cl-2 . 4H(2)O: triclinic space group P (1) over bar with a = 7.894(3) Angstrom, b = 7.981(3) Angstrom, c = 9.261(5) Angstrom, alpha = 65.41(3)degrees, beta = 79.97(4)degrees, gamma = 80.76(3)degrees, Z = 1). Its single-crystal vis-absorption spectrum showed three absorption bands (lambda 333 nm (epsilon 3.7), 507 (3.1), 667 (2.4)) in the range 300-800 nm.

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页码：6241 / 6243

页数：3

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