RING EXPANSION OR SPIROCYCLISATION OF (PHENYLTHIOMETHYLENE)CYCLOALKANES WITH ALUMINUM-CHLORIDE VIA BETA-THIO CARBOCATIONS

被引：4

作者：

DEROUANE, D ^{[1
]}

HARVEY, JN ^{[1
]}

VIEHE, HG ^{[1
]}

机构：

[1] UNIV CATHOLIQUE LOUVAIN,CHIM ORGAN LAB,B-1348 LOUVAIN,BELGIUM

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 10期

关键词：

D O I：

10.1039/c39950000993

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title reactions can be explained by Wagner-Meerwein rearrangement of alpha-thio carbocations (thionium ions) to beta-thio carbocations; this unusual reactivity may be due to superelectrophilic activation by aluminium chloride.

引用

页码：993 / 994

页数：2

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