ALKYNYLATION OF ORGANOMETALLIC SYSTEMS - A NEW, SIMPLE METHOD FOR THE INTRODUCTION OF TERMINAL ACETYLIDES - FORMATION OF RHODIUM(III) AND IRIDIUM(III) SIGMA-ACETYLIDE COMPLEXES

被引：48

作者：

STANG, PJ

CRITTELL, CM

机构：

[1] Department of Chemistry, The University of Utah, Salt Lake City

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 12期

关键词：

D O I：

10.1021/om00162a036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of trans -(Ph3P)2Ir(CO)(Cl) and trans -(Ph3P)2Rh(CO)(Cl) with RC≡CI+Ph·-OSO2CF3 in toluene at room temperature gives the corresponding iridium(III) and rodium(III) σ-acetylide complexes in 89-96% isolated yields. © 1990, American Chemical Society. All rights reserved.

引用

页码：3191 / 3193

页数：3

共 34 条

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