CONTROLLED SYNTHESIS OF (1,3-TERT-BU2-C5H3)2TICL2 AND (1,3-TERT-BU2-C5H3)TICL3 - CRYSTAL-STRUCTURE AND REACTIONS OF (1,3-TERT-BU2-C5H3)TICL3

被引：16

作者：

JIBRIL, I ^{[1
]}

ABUORABI, S ^{[1
]}

KLAIB, SA ^{[1
]}

IMHOF, W ^{[1
]}

HUTTNER, G ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 433卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80151-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compounds (1,3-tBu2C5H3)2TiCl2, (I) and (1,3-tBu2C5H3)TiCl3 (II) were prepared in good yields from TiCl4 and (1,3-tBu2-C5H3)Li. Reactions of II with methanol, ethane-1,2-diol, sodium oxalate, and 2-pyrazine carboxylic acid afforded various organotitanium complexes. The crystal structure of II was determined.

引用

页码：253 / 259

页数：7

共 24 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS

[2]

BAYRES LR, 1980, INORG CHEM, V9, P277

[3] THE PHOTOELECTRON-SPECTRA OF BIS(CYCLOPENTADIENYL)TITANIUM DERIVATIVES - A GREENS-FUNCTION APPROACH [J].

BOHM, MC .

INORGANICA CHIMICA ACTA-ARTICLES, 1982, 62 (02) :171-182

[4] ANTICANCER ACTIVITY OF ORGANOMETALLIC COMPOUNDS .1. SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF CYCLOPENTADIENYLTITANIUM AMINO AMIDO ACID COMPLEXES [J].

CARDIN, CJ ;

ROY, A .

INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1985, 107 (04) :L33-L35

[5] PREPARATION AND CHARACTERIZATION OF CARBOXYLATO DERIVATIVES OF BIS-(METHYL CYCLOPENTADIENYL) TITANIUM(IV) [J].

CHANDRA, K ;

SHARMA, RK ;

GARG, BS ;

SINGH, RP .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1980, 42 (02) :187-193

[6] ADDITION OF CROTYLTITANOCENES TO ALDEHYDES - INFLUENCE OF CYCLOPENTADIENYL SUBSTITUENTS ON THE DIASTEREOSELECTIVE FORMATION OF HOMOALLYLIC ALCOHOLS [J].

COLLINS, S ;

DEAN, WP ;

WARD, DG .

ORGANOMETALLICS, 1988, 7 (11) :2289-2293

[7] SOME NEW DERIVATIVES OF ORGANOZIRCONIUM(IV) AND ORGANOTITANIUM(IV) WITH PYRIDINECARBOXYLIC ACIDS [J].

DIXIT, SC ;

SHARAN, R ;

KAPOOR, RN .

INORGANICA CHIMICA ACTA, 1989, 158 (01) :109-113

[8] COMPARISON OF THE MOLECULAR-STRUCTURES AND INFRARED-SPECTRA OF TITANOCENE AND NIOBOCENE CHELATE TRIMETHYLACETATES [J].

EREMENKO, IL ;

SKRIPKIN, YV ;

PASYNSKII, AA ;

KALINNIKOV, VT ;

STRUCHKOV, YT ;

ALEKSANDROV, GG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 220 (02) :159-164

[9]

GANIS P, 1962, ATTI ACAD NAZ LINCEI, V33, P303

[10] CYCLIC CROSS-CONJUGATED BOND SYSTEMS .36. FIDECENES SYNTHESES, CYCLOADDITION REACTIONS [J].

KNOTHE, L ;

PRINZBACH, H ;

HADICKE, E .

CHEMISCHE BERICHTE-RECUEIL, 1981, 114 (05) :1656-1678

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