DISPROPORTIONATED FERRIC SULFIDE CATALYSTS FOR COAL-LIQUEFACTION

被引：21

作者：

DADYBURJOR, DB

STEWART, WR

STILLER, AH

STINESPRING, CD

WANN, JP

ZONDLO, JW

机构：

[1] West Virginia Univ, Morgantown, WV

来源：

ENERGY & FUELS | 1994年 / 8卷 / 01期

关键词：

Catalysts;

D O I：

10.1021/ef00043a003

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Above 5 degrees C, ferric sulfide disproportionates into mixtures of pyrite (PY), pyrrhotite (PH), and elemental S, with the relative amounts depending upon disproportionation temperature and time. The PH/PY mixtures are used as catalysts for coal liquefaction, with the optimum mixture corresponding to disproportionation at 200 degrees C for 1 h. Reactions of Fe during disproportionation and liquefaction are postulated and confirmed by AA, AES, and XRD. The iron loading has a nonlinear effect on conversion and yield.

引用

页码：19 / 24

页数：6

共 7 条

[1] THERMOMAGNETIC STUDIES OF CONVERSION OF PYRITE AND MARCASITE IN DIFFERENT ATMOSPHERES (VACUUM, H-2, HE AND CO) [J].