INVERSE CYCLOHEPTATRIENYL SANDWICH COMPLEXES - CRYSTAL-STRUCTURE OF [U(BH4)2(OC4H8)5][(BH4)3U(MU-ETA-7,ETA-7-C7H7)U(BH4)3]

被引:47
作者
ARLIGUIE, T [1 ]
LANCE, M [1 ]
NIERLICH, M [1 ]
VIGNER, J [1 ]
EPHRITIKHINE, M [1 ]
机构
[1] CEA CE SACLAY,SERV CHIM MOLEC,CRISTALLOG LAB,CNRS,URA 331,F-1191 GIF SUR YVETTE,FRANCE
关键词
D O I
10.1039/c39940000847
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The anions [X3U(mu-eta7,eta7-C7H7)UX3]- (X = NEt2 or BH4) have been obtained by treatment of UX4 with K[C7H9]; the cation [U(BH4)2(thf)5]+ was formed by protonation of [U(BH4)3(thf)3] with [NHEt3][BPh4] in tetrahydrofuran (thf).
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页码:847 / 848
页数:2
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