SODIUM-ION SENSING BY CELLULOSE TRIACETATE PLASTICIZER MEMBRANE CONTAINING DIBENZO-16-CROWN-5 CHROMOIONOPHORE

被引:26
作者
HAYASHITA, T
KUMAZAWA, M
LEE, JC
BARTSCH, RA
机构
[1] CHUNG ANG UNIV,DEPT CHEM,SEOUL 156756,SOUTH KOREA
[2] TEXAS TECH UNIV,DEPT CHEM & BIOCHEM,LUBBOCK,TX 79409
关键词
D O I
10.1246/cl.1995.711
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have designed new optical membrane sensor which is composed of cellulose triacetate polymer as a membrane support, o-nitophenyloctyl ether as a membrane plasticizer and sym-(decyl)(2-hydroxy-5-nitrobenzyloxy)dibenzo-16-crown-5 (1) as a Na+ ion selective chromoionophore. This type of membrane was found to selectively respond to Na+ in the detection limit of 10(-5) M (1 M = 1 mol dm(-3)) with no significant interference from Li+ and K+ ions.
引用
收藏
页码:711 / 712
页数:2
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