A CONVENIENT SYNTHESIS OF PERFLUOROALKYLATED ENAMINES AND VINYL PHOSPHONATES

被引：28

作者：

CEN, WB ^{[1
]}

NI, YH ^{[1
]}

SHEN, YC ^{[1
]}

机构：

[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,SHANGHAI 200032,PEOPLES R CHINA

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 73卷 / 02期

基金：

中国国家自然科学基金;

关键词：

SYNTHESIS; PERFLUOROALKYLATED ENAMINES; VINYL PHOSPHONATES; NMR SPECTROSCOPY; IR SPECTROSCOPY; MASS SPECTROMETRY;

D O I：

10.1016/0022-1139(95)03233-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of fluoroalkynes with ammonia and benzylamine gave perfluoroalkylated enamines predominantly as the Z isomer, which were hydrogenated with palladium on carbon to afford perfluoroalkylated beta-amino acids in good yield. The reaction of fluoroalkynes with diethyl phosphite afforded perfluoroalkylated vinyl phosphonates in moderate yield.

引用

页码：161 / 164

页数：4

共 14 条

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