HPLC DETERMINATION OF HYDROPEROXIDIC PRODUCTS FORMED IN THE AUTOXIDATION OF NORMAL-HEXADECANE AT ELEVATED-TEMPERATURES

被引：19

作者：

JENSEN, RK

ZINBO, M

KORCEK, S

机构：

来源：

JOURNAL OF CHROMATOGRAPHIC SCIENCE | 1983年 / 21卷 / 09期

关键词：

HYDROCARBONS - Chromatographic Analysis;

D O I：

10.1093/chromsci/21.9.394

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

HPLC procedures were developed for direct analysis of hydroperoxidic products formed during the autoxidation of n-hexadecane at elevated temperatures. These procedures use both normal and reversed-phase HPLC with Radial-PAK cartridges and ultraviolet detection at 254 nm. They allow quantitative determination of individual and total isomeric hexadecylhydroperoxides and semiquantitative estimation of isometric hydroperoxyhexadecanones and hexadecanedihydroperoxides. The main procedure used does not require either chemical pretreatment or prior enrichment.

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收藏

页码：394 / 397

页数：4

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