AN OPTICAL SENSOR FOR THE DETECTION OF CD(II) IONS

被引:10
作者
CZOLK, R
REICHERT, J
ACHE, HJ
机构
[1] Kernforschunszentrum Karlsruhe GmbH, Institut für Radiochemie, D- 7500 Karlsruhe
关键词
D O I
10.1016/0924-4247(91)87028-2
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
5,10,15,20-meso-tetra(p-sulfonatophenyl)-porphyrin is a highly sensitive indicator for the determination of Cd(II) ions in alkaline solutions. After immobilizing this dye in a poly(vinychloride) membrane, its application as a chromoionophore in combination with tridodecylmethylammonium-chloride as co-ionophore is investigated. The response time of this sensor is 20 min after contact with Cd(II) solutions and is reversible. The detection limit is 1.9 x 10(-5) mol/l (2.1 mg/l).
引用
收藏
页码:439 / 441
页数:3
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MOORE, FL .
ANALYTICAL CHEMISTRY, 1973, 45 (06) :983-985
[3]  
TAN SSS, 1989, CHIMIA, V43, P257