[2.2]PARACYCLOPHANE AS A FACE-CAPPING LIGAND - CONFORMATIONAL VARIABILITY OVER THE RUTHENIUM TRIANGLE

被引：25

作者：

DYSON, PJ

JOHNSON, BFG

MARTIN, CM

BLAKE, AJ

BRAGA, D

GREPIONI, F

PARISINI, E

机构：

[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,SCOTLAND

[2] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 05期

关键词：

D O I：

10.1021/om00017a083

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The three new [2,2] paracyclophane clusters Ru(3)(CO)9(mu3-eta2:eta2:eta2-C16H16) (1), Ru6C(CO)11(mu3-eta2:eta2:eta2-C16H16)(eta6C16H16) (3), and Ru6(C)(CO)12(mu3-eta2:eta2:eta2-C16H16)-(mu2-eta2:eta2-C6H8) (4) have been prepared and characterized spectroscopically. The structures of compounds 3 and 4 have also been analyzed by X-ray diffraction methods. A comparison of the face-capping ligand in these species, together with the known complex Ru6C(CO)14(mu3-eta2:eta2: eta2-C16H16) (2) leads to the observation that the [2.2]-paracyclophane ring bonds to the triruthenium face in a range of differing orientations, from near-staggered to near-eclipsed.

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页码：2113 / 2117

页数：5

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