A comparison of the rates of alkyl migration in the complexes [CpM(CO)(2)R](M=Fe,Ru,Os; Cp=eta(5)-C5H5)

被引:24
作者
George, R [1 ]
Andersen, JAM [1 ]
Moss, JR [1 ]
机构
[1] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA
关键词
iron; ruthenium; osmium; cyclopentadienyl; alkyl migration; carbonyl;
D O I
10.1016/0022-328X(95)05898-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The rates of alkyl migration for selected members of the series [CpM(CO)(2)R] (M = Fe, Ru, Os; Cp = eta(5)-C5H5,; R = CH3 ton-C18H37) show dependence on both the alkyl group and the metal.
引用
收藏
页码:131 / 133
页数:3
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