DISPIROMACROCYCLES - A CLASS OF DIAMIDE AND DIIMIDE IONOPHORES

被引：9

作者：

BELL, TW

CHOI, HJ

HIEL, G

机构：

[1] Department of Chemistry, State Uniniversity of New York, Stony Brook

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 06期

关键词：

MACROCYCLIZATION; LITHIUM; ION-SELECTIVE; ELECTRODE; SPIRODIAMIDE;

D O I：

10.1016/S0040-4039(00)77468-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of novel ionophores was synthesized in three steps from acrylonitrile and diethyl malonate or malononitrile via 2,8-diazaspiro[5,5]undecane-1,7-dione (7) or 2,8-diazaspiro[5,5]undecane-1,3,7,9-tetrone (8). Spirodiamide macrocycle 14 imparts selectivity for lithium to potentiometric ion-selective electrodes.

引用

页码：971 / 974

页数：4

共 13 条

[1]

BELL TW, 1992, Patent No. 5128466

[2]

BIRCH NJ, 1991, ADV INORG CHEM, V36, P49

[3] LIPOPHILIC DIAMIDES AS IONOPHORES FOR ALKALI AND ALKALINE-EARTH METAL-CATIONS [J].