ADDITIONS OF CARBANIONS TO A CATIONIC CYCLOPENTADIENYL(NAPHTHALENE)IRON COMPLEX

被引：12

作者：

KUNDIG, EP ^{[1
]}

JEGER, P ^{[1
]}

BERNARDINELLI, G ^{[1
]}

机构：

[1] UNIV GENEVA,CRYSTALLOG LAB,CH-1211 GENEVA 4,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 19期

关键词：

ARENE COMPLEXES; IRON COMPOUNDS; HAPTOTROPIC REARRANGEMENTS; NUCLEOPHILIC ADDITIONS;

D O I：

10.1002/anie.199521611

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple change in the substitution pattern of the naphthalene ligand can effectively alter the reaction pathway: the reaction of [Cp(naphthalene)Fe]PF6 with carbon nucleophiles results in reduction of the Fe center, but complex 1 reacts with PhLi by nucleophilic addition at the condensed arene. When tBuLi is used as the nucleophile, addition to the Cp ring of 1 giving 2 is observed instead. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2161 / 2163

页数：3

共 27 条

[1] RESOLUTION AND ASYMMETRIC-SYNTHESIS OF ORTHO-SUBSTITUTED (BENZALDEHYDE)TRICARBONYLCHROMIUM COMPLEXES [J].

ALEXAKIS, A ;

MANGENEY, P ;

MAREK, I ;

ROSEMUNCH, F ;

ROSE, E ;

SEMRA, A ;

ROBERT, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (21) :8288-8290

[2]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[3] 19-ELECTRON COMPLEXES AND THEIR ROLE IN ORGANOMETALLIC MECHANISMS [J].

ASTRUC, D .

CHEMICAL REVIEWS, 1988, 88 (07) :1189-1216

[4] ORGANO IRON COMPLEXES OF AROMATIC-COMPOUNDS - APPLICATIONS IN SYNTHESIS [J].

ASTRUC, D .

TETRAHEDRON, 1983, 39 (24) :4027-4095

[5] THE EVALUATION OF TRANSMISSION FACTORS AND THEIR 1ST DERIVATIVES WITH RESPECT TO CRYSTAL SHAPE-PARAMETERS [J].

BLANC, E ;

SCHWARZENBACH, D ;

FLACK, HD .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1991, 24 :1035-1041

[6] SEQUENTIAL FRIEDEL-CRAFTS DIACETYLATION OF FERROCENE - INTERANNULAR PROTON TRANSFERS AS A MECHANISTIC PROBE [J].

CUNNINGHAM, AF .

ORGANOMETALLICS, 1994, 13 (06) :2480-2485

[7] NUCLEOPHILIC-ADDITION TO ORGANOTRANSITION METAL-CATIONS CONTAINING UNSATURATED HYDROCARBON LIGANDS - SURVEY AND INTERPRETATION [J].

DAVIES, SG ;

GREEN, MLH ;

MINGOS, DMP .

TETRAHEDRON, 1978, 34 (20) :3047-3077

[8]

DOGGWEILER HO, 1988, Patent No. 270490

[9] PHOTOCHEMICAL GENERATION OF A REACTIVE TRANSITION-METAL FRAGMENT - PHOTOCHEMICALLY INDUCED ARENE REPLACEMENT REACTIONS OF THE CYCLOPENTADIENYL(PARA-XYLENE)IRON(II) ION [J].

GILL, TP ;

MANN, KR .

INORGANIC CHEMISTRY, 1980, 19 (10) :3007-3010

[10]

HALL SR, 1992, XTAL3 2 USERS MANUAL

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