NEW METHODS OF PREPARING F-ALKYL OXIRANES FROM 2-BROMO-2-F-ALKYLETHYL ACETATES AND 2-BROMO-2-F-ALKYLETHANOLS

被引:27
作者
CHAABOUNI, MM [1 ]
BAKLOUTI, A [1 ]
SZONYI, S [1 ]
CAMBON, A [1 ]
机构
[1] UNIV NICE,CHIM ORGAN FLUOR LAB,F-06034 NICE,FRANCE
关键词
D O I
10.1016/S0022-1139(00)80998-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
F-alkyl oxiranes provide many interesting intermediates. Their synthesis from 2-bromo-2-F-alkylethyl acetates and from 2-bromo-2-F-alkylethanols was improved by two different methods which are very easy to apply. One requires the use of concentrated caustic soda and a phase transfer catalysts; the other one, potassium fluoride in triethylene glycol. © 1990.
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页码:307 / 315
页数:9
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