PERCHLORINATED AND HIGHLY CHLORINATED MESO-TETRAPHENYLPORPHYRINS

被引：122

作者：

WIJESEKERA, T

MATSUMOTO, A

DOLPHIN, D

LEXA, D

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,2036 MAIN MALL,VANCOUVER V6T 1W5,BC,CANADA

[2] UNIV PARIS 07,ELECTROCHIM LAB,F-75230 PARIS 05,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 09期

关键词：

D O I：

10.1002/anie.199010281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electron‐withdrawing chloro substituents in the porphinatoiron(III) compounds 2–6 cause anodic shifts in the half‐wave potentials E1/2 relative to that of the unsubstituted compound 1. Substitution on the phenyl rings is less effective than β substitution (R3). The spectroelectrochemically determined stability constants for binding of Cl⊖ are high for the β‐chlorinated derivatives. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1028 / 1030

页数：3

共 14 条

[1] ON PREPARATION OF METALLOPORPHYRINS
ADLER, AD
LONGO, FR
KAMPAS, F
KIM, J
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1970, 32 (07): : 2443 - &
[2] COUNTERION AND SOLVENT EFFECTS ON THE ELECTRODE-REACTIONS OF IRON PORPHYRINS
BOTTOMLEY, LA
KADISH, KM
[J]. INORGANIC CHEMISTRY, 1981, 20 (05) : 1348 - 1357
[3] CALLOT HJ, 1974, B SOC CHIM FR II-CH, P1492
[4] CONTROL OF REACTIVITY AT THE PORPHYRIN PERIPHERY BY METAL-ION COORDINATION - A GENERAL-METHOD FOR SPECIFIC NITRATION AT THE BETA-PYRROLIC POSITION OF 5,10,15,20-TETRA-ARYLPORPHYRINS
CATALANO, MM
CROSSLEY, MJ
HARDING, MM
KING, LG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (22) : 1535 - 1536
[5] CHARACTERIZATION OF SINGLY REDUCED IRON(II) PORPHYRINS
DONOHOE, RJ
ATAMIAN, M
BOCIAN, DF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) : 5593 - 5599
[6] EFFECTS OF ELECTRON-WITHDRAWING SUBSTITUENTS ON THE ELECTROCHEMICAL OXIDATION OF PORPHYRINS
GIRAUDEAU, A
CALLOT, HJ
GROSS, M
[J]. INORGANIC CHEMISTRY, 1979, 18 (01) : 201 - 206
[7] SUBSTITUENT EFFECTS IN THE ELECTROREDUCTION OF PORPHYRINS AND METALLOPORPHYRINS
GIRAUDEAU, A
CALLOT, HJ
JORDAN, J
EZHAR, I
GROSS, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (14) : 3857 - 3862
[8] NITROOCTAETHYLPORPHYRINS - SYNTHESIS, OPTICAL AND REDOX PROPERTIES
GONG, LC
DOLPHIN, D
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1985, 63 (02): : 401 - 405
[9] MOLECULAR ENVIRONMENT EFFECTS OF REDOX AND COORDINATION CHEMISTRY - PROTECTION AGAINST SOLVATION, LOCAL SOLVATION, AND STERIC HINDRANCE TO LIGATION IN THE ELECTROCHEMISTRY OF BASKET-HANDLE IRON PORPHYRINS
GUEUTIN, C
LEXA, D
MOMENTEAU, M
SAVEANT, JM
XU, F
[J]. INORGANIC CHEMISTRY, 1986, 25 (23) : 4294 - 4307
[10] THIN-LAYER SPECTROELECTROCHEMICAL EVIDENCE OF ANION BINDING TO (TETRAPHENYLPORPHINATO)IRON(II) IN NON-AQUEOUS MEDIA
KADISH, KM
RHODES, RK
[J]. INORGANIC CHEMISTRY, 1983, 22 (07) : 1090 - 1094

← 1 2 →