THE TETRAPHENYLESTER OF THE MU-IMIDO-DITHIODIPHOSPHORIC ACID AND ITS PALLADIUM COMPLEX - CRYSTAL-STRUCTURES

被引：18

作者：

NOUAMAN, M

ZAK, Z

HERRMANN, E

NAVRATIL, O

机构：

[1] MASARYK UNIV BRNO, INST INORGAN CHEM, BRNO, CZECHOSLOVAKIA

[2] MIL COLL, INST SPECIAL CHEM, VYSKOV, CZECHOSLOVAKIA

[3] MARTIN LUTHER UNIV HALLE WITTENBERG, INST INORGAN CHEM, O-4010 HALLE, GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 06期

关键词：

O; O'; O''; O'''-TETRAPHENYL MU-IMIDO-DITHIODIPHOSPHATE; N-(O; O'-DIPHENYLTHIOPHOSPHORYL)-O''; O'''-DIPHENYLTHIOPHOSPHORIMIDATE; BIS(O; O'''-TETRAPHENYL MU-IMIDO-DITHIODIPHOSPHATO) PALLADIUM CHELATE; BIS[N-(O; O'''-DIPHENYLTHIOPHOSPHORIMIDATO] PALLADIUM CHELATE; PREPARATION; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19936190630

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparations of [(C6H5O)2PS]2NH (SS) and its Pd complex [Pd{C6H5O)2P(S)NP(S)(OC6H5)2}2] (PDSS) are described. The compounds were characterized by elemental analysis, NMR, and mass spectra and X-ray structure analysis. The structure of SS contains two independent molecules in an asymmetric unit which are joined into dimers via N ... H ... S hydrogen bonds. SS is a Bronsted acid and reacts with Pd(II) to a neutral chelate complex. The structure of PDSS is composed of isolated molecules with Pd atom in the center of symmetry. The Pd atom is coordinated by 4 S atoms in a distorted square-planar arrangement with average distance Pd-S 2.345(6) angstrom and an angle S-Pd-S 98.29(4)-degrees.

引用

页码：1147 / 1153

页数：7

共 15 条

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