COBALT(II) CHLORIDE CATALYZED CONVERSION OF ALLYLIC ALCOHOLS TO REARRANGED ALLYLIC AMIDES

被引：16

作者：

NAYYAR, NK ^{[1
]}

REDDY, MM ^{[1
]}

IQBAL, J ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 47期

关键词：

D O I：

10.1016/0040-4039(91)80456-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Secondary and tertiary allylic alcohols can be converted to the corresponding allylically rearranged amides and acetates in presence of a catalytic quantity of cobalt(II) chloride and acetic anhydride in acetonitrile. Tertiary alcohols undergo complete rearrangement whereas the secondary ones yield a mixture of regioisomers.

引用

页码：6965 / 6968

页数：4

共 16 条

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