A NEW TETRADENTATE NITROGEN LIGAND FOR ORGANOMETALLIC CATALYSIS - ELECTROCHEMICAL NICKEL-CATALYZED INTRAMOLECULAR CYCLIZATION

被引：14

作者：

CLINET, JC

DUNACH, E

机构：

[1] UNIV NICE,CHIM MOLEC LAB,CNRS,URA 426,F-06108 NICE 02,FRANCE

[2] UNIV PARIS 11,INST CHIM MOLEC,CNRS,URA 1497,F-91405 ORSAY,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 503卷 / 02期

关键词：

NITROGEN LIGAND; TETRADENTATE; NICKEL CATALYSIS; INTRAMOLECULAR CYCLIZATION;

D O I：

10.1016/0022-328X(95)05838-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new tetraaza-molecule, 1 has been synthesized and used as a ligand for a cationic mononuclear nickel(II) complex. This complex is an efficient catalysts for the intramolecular electrochemical cyclization of o-haloaryl compounds containing unsaturated side chains.

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收藏

页码：C48 / C50

页数：3

相关论文

共 23 条

[1]

ADAM KR, 1991, J CHEM SOC DA, V10, P2493

[2] PALLADIUM-CATALYZED ASYMMETRIC ALLYLIC SUBSTITUTION - A LIGAND DESIGN INCORPORATING STERIC AND ELECTRONIC EFFECTS [J].

ALLEN, JV ;

COOTE, SJ ;

DAWSON, GJ ;

FROST, CG ;

MARTIN, CJ ;

WILLIAMS, JMJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (15) :2065-2072

[3] ELECTROCATALYTIC REDUCTION OF CO2 BY NI CYCLAM2+ IN WATER - STUDY OF THE FACTORS AFFECTING THE EFFICIENCY AND THE SELECTIVITY OF THE PROCESS [J].

BELEY, M ;

COLLIN, JP ;

RUPPERT, R ;

SAUVAGE, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (24) :7461-7467

[4] BIS(4,5-DIHYDROOXAZOLYL) DERIVATIVES IN ASYMMETRIC CATALYSIS [J].

BOLM, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (05) :542-543

[5]

CHAUSSARD J, 1990, SYNTHESIS-STUTTGART, V5, P369

[6] FROM STOICHIOMETRY TO CATALYSIS - ELECTROREDUCTIVE COUPLING OF ALKYNES AND CARBON-DIOXIDE WITH NICKEL BIPYRIDINE COMPLEXES - MAGNESIUM-IONS AS THE KEY FOR CATALYSIS [J].

DERIEN, S ;

DUNACH, E ;

PERICHON, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (22) :8447-8454

[7] ACTIVATION OF CARBON-DIOXIDE - NICKEL-CATALYZED ELECTROCHEMICAL CARBOXYLATION OF DIYNES [J].

DERIEN, S ;

CLINET, JC ;

DUNACH, E ;

PERICHON, J .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (09) :2578-2588

[8] THE CHEMISTRY OF 2-OXAZOLINES (1985-PRESENT) [J].

GANT, TG ;

MEYERS, AI .

TETRAHEDRON, 1994, 50 (08) :2297-2360

[9] CATALYSIS OF THE ELECTROCHEMICAL REDUCTION OF ALKYL BROMIDES BY NICKEL-COMPLEXES - FORMATION OF CARBON-CARBON BONDS [J].

GOSDEN, C ;

PLETCHER, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 186 (03) :401-409

[10] CHEMISTRY OF ELECTROGENERATED TRANSITION-METALS SPECIES - INSERTION OF OLEFINS INTO A NICKEL-CARBON BOND [J].

HEALY, KP ;

PLETCHER, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 161 (01) :109-120