CYCLOPENTADIENYL-RUTHENIUM AND -OSMIUM CHEMISTRY .35. SOME ETHYNYL, VINYLIDENE AND RELATED COMPLEXES

被引：58

作者：

BRUCE, MI

KOUTSANTONIS, GA

机构：

[1] Jordan Laboratories, Department of Physical and Inorganic Chemistry, University of Adelaide

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1991年 / 44卷 / 02期

关键词：

D O I：

10.1071/CH9910207

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses of several vinylidene- and ethynyl-ruthenium complexes are described, starting from HC2SiMe3 and RuCI(L)2(eta-C5H5) (L = PPh3, PMe3; L2 = dppe). Their properties and some reactions are reported. The metallacyclic complex [Ru{C4H2(SiMe3)2}(PMe3)(eta-C5H5)][PF6] has also been isolated. The unsubstituted complexes are very reactive; for example, MeOH adds rapidly to the vinylidene to form the C(OMe)Me derivative.

引用

页码：207 / 217

页数：11

共 24 条

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[2]

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