MINERALOGY AND POSSIBLE ORIGIN OF AN UNUSUAL CR-RICH INCLUSION IN THE LOS MARTINEZ (L6) CHONDRITE

During a petrological study of the previously unclassified ordinary chondrite Los Martinez, we discovered a highly unusual Cr-rich inclusion which we believe is unique in both extraterrestrial and terrestrial mineralogy. The inclusion is highly zoned both compositionally and optically, with a Ca-Al rich, cloudy core and an opaque, Cr-Na-rich rim (up to 24 wt.% Cr2O3). Detailed SEM and TEM studies show that the inclusion now consists of a highly zoned, single crystal of plagioclase intergrown with chromium-rich spinel. The spinel has a well-developed crystallographic orientation relationship with the host plagioclase, which indicates that it is the product of exsolution. Although superficially similar to a plagioclase feldspar in composition, in detail the inclusion is Si-deficient and Al-enriched relative to a stoichiometric feldspar. We have not been able to identify a viable precursor mineral phase to the plagioclase-chromite intergrowth and suggest that it may be an unknown metastable phase. The Cr-rich precursors of the inclusion probably have close affinities to the chromite-plagioclase chondrules observed by Ramdohr (1967) in several ordinary chondrites. Based on the zoning in the inclusion, we suggest that it is the product of fractional crystallization from a melt, which may have formed as a liquid condensate, or by melting of solid condensates, in the solar nebula. Subsequent cooling of this melt condensate resulted in crystallization of the, as yet, unidentified phase. After crystallization, the inclusion was probably incorporated into a parent body where it underwent metamorphism and was probably shocked to some degree. During this period of parent body metamorphism, exsolution and decomposition of the unknown precursor occurred to produce the observed intergrowth of plagioclase and chromite. Finally, we have classified Los Martinez as an L6 ordinary chondrite breccia.