THE SURPRISINGLY FACILE DEHYDROHALOGENATION OF A HYDRAZONOYL CHLORIDE INTO A STABLE PHOSPHORUS-SUBSTITUTED NITRILIMINE

被引：4

作者：

CASTAN, F

BACEIREDO, A

DAHAN, F

AUNER, N

BERTRAND, G

机构：

[1] CNRS,CHIM COORDINAT LAB,205 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

[2] TECH UNIV MUNICH,INST ANORGAN CHEM,W-8046 GARCHING,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 17期

关键词：

D O I：

10.1039/c39920001274

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetrachloro-o-benzoquinone reacts with bis(diisopropylamino)thioxophosphoranenitrile N-[(phenyl)(2,4,6,-trifluoromethylphenyl)phosphanyl]imide 1b affording the corresponding sigma-5-lambda-5-phosphorus-substituted nitrilimine 2b; addition of HCl to 2b leads to hydrazonoyl chloride 4b which gives back nitrilimine 2b by simple filtration on silica gel.

引用

页码：1274 / 1276

页数：3

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