THE SURPRISINGLY FACILE DEHYDROHALOGENATION OF A HYDRAZONOYL CHLORIDE INTO A STABLE PHOSPHORUS-SUBSTITUTED NITRILIMINE

被引:4
作者
CASTAN, F
BACEIREDO, A
DAHAN, F
AUNER, N
BERTRAND, G
机构
[1] CNRS,CHIM COORDINAT LAB,205 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE
[2] TECH UNIV MUNICH,INST ANORGAN CHEM,W-8046 GARCHING,GERMANY
关键词
D O I
10.1039/c39920001274
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tetrachloro-o-benzoquinone reacts with bis(diisopropylamino)thioxophosphoranenitrile N-[(phenyl)(2,4,6,-trifluoromethylphenyl)phosphanyl]imide 1b affording the corresponding sigma-5-lambda-5-phosphorus-substituted nitrilimine 2b; addition of HCl to 2b leads to hydrazonoyl chloride 4b which gives back nitrilimine 2b by simple filtration on silica gel.
引用
收藏
页码:1274 / 1276
页数:3
相关论文
共 19 条
  • [1] SYNTHESIS OF STABLE BORYL-SUBSTITUTED DIAZOMETHANE AND NITRILIMINES
    ARTHUR, MP
    GOODWIN, HP
    BACEIREDO, A
    DILLON, KB
    BERTRAND, G
    [J]. ORGANOMETALLICS, 1991, 10 (09) : 3205 - 3210
  • [2] Caramella P., 1984, 1 3 DIPOLAR CYCLOADD
  • [3] A DISTILLABLE C-SILYLATED AND N-SILYLATED NITRILE IMINE
    CASTAN, F
    BACEIREDO, A
    BERTRAND, G
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (09): : 1250 - 1251
  • [4] SYNTHESIS AND REACTIVITY OF STABLE SILYL-SUBSTITUTED NITRILIMINES
    CASTAN, F
    BACEIREDO, A
    BIGG, D
    BERTRAND, G
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (05) : 1801 - 1807
  • [5] 1.3-DIPOLARE CYCLOADDITIONEN .25. DER NACHWEIS DES FREIEN DIPHENYLNITRILIMINS ALS ZWISCHENSTUFE BEI CYCLOADDITIONEN
    CLOVIS, JS
    ECKELL, A
    HUISGEN, R
    SUSTMANN, R
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1967, 100 (01): : 60 - &
  • [6] ENDERS E, 1967, METHODEN ORG CHEM, V10
  • [7] 1ST DIRECT EVIDENCE FOR NITRILE IMINE DIAZO ISOMERIZATION - SYNTHESIS OF RELATIVELY STABLE N-SILYLATED NITRILE IMINES
    GRANIER, M
    BACEIREDO, A
    BERTRAND, G
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (10): : 1350 - 1351
  • [8] DIRECT EVIDENCE FOR A NITRILE IMINE IMIDOYLNITRENE REARRANGEMENT - X-RAY CRYSTAL-STRUCTURE OF AN UNUSUAL NITRENE COMPLEX
    GRANIER, M
    BACEIREDO, A
    GRUTZMACHER, H
    PRITZKOW, H
    BERTRAND, G
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (06): : 659 - 661
  • [9] SYNTHESIS AND REACTIVITY OF STABLE PHOSPHORUS-SUBSTITUTED NITRILIMINES - X-RAY CRYSTAL-STRUCTURE OF C-[BIS(DIISOPROPYLAMINO)THIOXOPHOSPHORANYL]-N-[BIS(DIISOPROPYLAMINO)PHOSPHANYL]NITRILIMINE
    GRANIER, M
    BACEIREDO, A
    DARTIGUENAVE, Y
    DARTIGUENAVE, M
    MENU, MJ
    BERTRAND, G
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (17) : 6277 - 6285
  • [10] X-RAY CRYSTAL-STRUCTURE AND REACTIVITY OF AN N-PHOSPHONIO-SUBSTITUTED NITRILIMINE - A STABLE ELECTROPHILIC NITRILIMINE
    GRANIER, M
    BACEIREDO, A
    BERTRAND, G
    HUCH, V
    VEITH, M
    [J]. INORGANIC CHEMISTRY, 1991, 30 (06) : 1161 - 1162