METAL-CATALYZED CARBON-CARBON BOND FORMATION IN THE REACTION OF BETA-DICARBONYLS WITH NITRILES

被引：59

作者：

CORAIN, B ^{[1
]}

BASATO, M ^{[1
]}

VERONESE, AC ^{[1
]}

机构：

[1] UNIV FERRARA,DIPARTIMENTO SCI FARMACEUT,I-44100 FERRARA,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 81卷 / 02期

关键词：

BETA-CARBONYLENOLATO COMPLEXES; BETA-IMINOENOLATO COMPLEXES; CARBON CARBON BOND FORMATION; BETA-DICARBONYLS; METAL CATALYSIS; NITRILES; REVIEW;

D O I：

10.1016/0304-5102(93)80002-C

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new synthetic procedure to carbon-carbon bond formation between C-H acidic compounds and nucleophiles, like Michael acceptors and nitriles, is based on the use of metal (II) centres as catalysts in a homogeneous phase. The contributions to the inorganic, organic and mechanistic aspects of the reaction of beta-dicarbonyls with nitriles are reviewed. Metal catalysis appears, for the investigated systems, largely superior to the traditional approach, which employs organic bases as catalysts, and the perspectives of an extension of this metal-catalysed procedure are illustrated.

引用

页码：133 / 155

页数：23

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