PHTHALIMIDESULFENYL CHLORIDE .8. REACTION WITH ACTIVATED ARENES - THE FIRST EXAMPLE OF ORTHO-THIOQUINONES GENERATION

被引：26

作者：

CAPOZZI, G ^{[1
]}

MENICHETTI, S ^{[1
]}

NATIVI, C ^{[1
]}

SIMONTI, MC ^{[1
]}

机构：

[1] UNIV FLORENCE,CNR,CTR CHIM COMPOSTI ETEROCICLICI,DIPARTIMENTO CHIM ORGAN,I-50121 FLORENCE,ITALY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(00)78568-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phthalimidesulfenyl chloride 1 reacts with activated arenes 2a-g, to give monosubstituted derivatives 3a-g. Hydroxysulfenyl compounds 3a-d have been used as suitable source of alpha-oxothiones (ortho-thioquinones) 4a-d, which act as heterodienes in 4+2 cycloaddition reactions.

引用

页码：9451 / 9454

页数：4

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