INTEGRATED ELECTROMODULATED IR REFLECTANCE SPECTROSCOPY (EMIRS) .1. NOISE-REDUCTION AND BETTER ACCURACY IN THE DETERMINATION OF EMIRS BAND CENTERS

被引：14

作者：

BEDEN, B

机构：

[1] Laboratoire de chimie 1, Electrochimie et Interactions, UA CNRS 350, 86022 Poitiers

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1993年 / 345卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(93)80465-T

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The advantages of using integrated electromodulated IR reflectance spectroscopy (EMIRS) bands are examined in the light of theoretical and practical considerations of the shapes of EMIRS bands. As a result of noise reduction and ease of location of the band centres, it is demonstrated by using several examples that the integration method leads to a real improvement in the quality of EMIRS spectra, allowing far more directly accessible and reliable interpretations.

引用

页码：1 / 12

页数：12

共 43 条

[1] THE EFFECT OF SOLVENT TYPE ON THE INFRARED-SPECTRUM OF CARBON-MONOXIDE ADSORBED AT PLATINUM-ELECTRODES
ANDERSON, MR
BLACKWOOD, D
RICHMOND, TG
PONS, S
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 256 (02): : 397 - 403
[2] INFRARED SPECTROSCOPIC STUDY OF THE METHANOL ADSORBATES AT A PLATINUM-ELECTRODE .1. INFLUENCE OF THE BULK CONCENTRATION OF METHANOL UPON THE NATURE OF THE ADSORBATES
BEDEN, B
HAHN, F
JUANTO, S
LAMY, C
LEGER, JM
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 225 (1-2): : 215 - 225
[3] INFRARED STUDY OF ADSORBED SPECIES ON ELECTRODES - ADSORPTION OF CARBON-MONOXIDE ON PT, RH AND AU
BEDEN, B
BEWICK, A
KUNIMATSU, K
LAMY, C
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 142 (1-2): : 345 - 356
[4] INSITU INFRARED REFLECTANCE SPECTROSCOPIC STUDY OF THE ADSORBED SPECIES RESULTING FROM CH3OH ADSORPTION ON POLYCRYSTALLINE PT IN ACID-SOLUTION
BEDEN, B
HAHN, F
LEGER, JM
LAMY, C
LOPES, MIDS
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 258 (02) : 463 - 467
[5] INFRARED SPECTROSCOPIC STUDY OF THE METHANOL ADSORBATES AT A PLATINUM-ELECTRODE .3. STRUCTURAL EFFECTS AND BEHAVIOR OF A POLYCRYSTALLINE SURFACE
BEDEN, B
JUANTO, S
LEGER, JM
LAMY, C
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 238 (1-2): : 323 - 331
[6] BEDEN B, 1981, J ELECTROANAL CHEM, V121, P343, DOI 10.1016/0368-1874(81)80026-3
[7] Beden B., 1992, MOD ASPECT ELECTROC, V22, P97, DOI DOI 10.1007/978-1-4615-3376-4_2
[8] BEDEN B, 1990, NATO ASI SER C-MATH, V320, P103
[9] Beden B., 1988, SPECTROELECTROCHEMIS, P189, DOI 10.1007/978-1-4613-0985-7_5
[10] ELECTROCHEMICALLY MODULATED INFRARED-SPECTROSCOPY (EMIRS) - EXPERIMENTAL DETAILS
BEWICK, A
KUNIMATSU, K
PONS, BS
RUSSELL, JW
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 160 (1-2): : 47 - 61

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