DICYCLOHEXYLDITHIOPHOSPHINATES AND DIETHYLDITHIOPHOSPHINATES OF METHYLMERCURY(II) AND PHENYLMERCURY(II) - CRYSTAL AND MOLECULAR-STRUCTURE OF [HGPH(S2PET2)]

被引：24

作者：

CASAS, JS

CASTINEIRAS, A

SANCHEZ, A

SORDO, J

VAZQUEZLOPEZ, EM

机构：

[1] Departamento de Química Inorgánica, Facultade de Farmacia, Universidade de Santiago de Compostela, 15706 Santiago de Compostela, Galicia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 468卷 / 1-2期

关键词：

MERCURY; METHYL; PHENYL; DITHIOPHOSPHINATE; DITHIOLATE; X-RAY DIFFRACTION;

D O I：

10.1016/0022-328X(94)80022-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methylmercury(II) and phenylmercury(II) dithiophosphinates [HgR(S2PR2')] (R = Me or Ph; R' = Et or Cy) were synthesized. In [HgPh(S2PEt2)] the mercury atom is coordinated to a phenyl carbon atom and to one S atom of the dithiophosphinate (Hg-C, 2.07(2) angstrom, Hg-S, 2.375(3) angstrom). The other sulphur atom of the dithiophosphinate forms two weak Hg...S interactions, one intramolecular and other intermolecular (Hg-S, 3.182(3) angstrom and 3.183(3) angstrom respectively). The mass, IR, Raman and H-1, C-13, P-31 and Hg-199 nuclear magnetic resonance spectra of the compounds are discussed.

引用

页码：1 / 6

页数：6

共 26 条

[1] METAL-SILICON BONDED COMPOUNDS .18. A HG-199 FT NMR-STUDY OF SOME SILYLMERCURY DERIVATIVES AND SELECTED ORGANOMERCURY COMPOUNDS [J].

ALBRIGHT, MJ ;

SCHAAF, TF ;

HOVLAND, AK ;

OLIVER, JP .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 259 (01) :37-50

[2] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[3] METHYLMERCURY(II) AND PHENYLMERCURY(II) DERIVATIVES OF 2-MERCAPTOBENZOTHIAZOLE - CRYSTAL-STRUCTURE OF (2-MERCAPTOBENZOTHIAZOLATO)METHYLMERCURY(II) [J].

BRAVO, J ;

CASAS, JS ;

CASTANO, MV ;

GAYOSO, M ;

MASCARENHAS, YP ;

SANCHEZ, A ;

SANTOS, CDP ;

SORDO, J .

INORGANIC CHEMISTRY, 1985, 24 (21) :3435-3438

[4] C-13 NUCLEAR MAGNETIC-RESONANCE STUDY OF METHYL-MERCURY(II) AND PHENYL-MERCURY(II) COMPOUNDS [J].

BROWN, AJ ;

HOWARTH, OW ;

MOORE, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (16) :1589-1592

[5] METAL-ION - BIOMOLECULE INTERACTIONS .10. SYNTHESIS, SPECTROSCOPIC AND MAGNETIC-RESONANCE INVESTIGATIONS OF METHYLMERCURY(II) COMPLEXES OF THE SULFUR MODIFIED NUCLEOSIDES 6-MERCAPTOPURINE RIBOSIDE AND 2-AMINO-6-MERCAPTOPURINE RIBOSIDE [J].

BUNCEL, E ;

KUMAR, R ;

NORRIS, AR .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1986, 64 (03) :442-448

[6] MERCURY(II) AND ORGANOMERCURY(II) COMPLEXES OF THIOLS AND DITHIOLS, INCLUDING BRITISH ANTI-LEWISITE [J].

CANTY, AJ ;

KISHIMOTO, R .

INORGANICA CHIMICA ACTA, 1977, 24 (02) :109-122

[7] VIBRATIONAL AND NMR SPECTROSCOPIC STUDIES OF CADMIUM(II) BIS (DIALKYL DITHIOPHOSPHINATES) [J].

CASAS, JS ;

GARCIATASENDE, MS ;

SANCHEZ, A ;

SORDO, J ;

VAZQUEZLOPEZ, EM ;

CASTELLANO, EE ;

ZUKERMANSCHPECTOR, J .

INORGANICA CHIMICA ACTA, 1993, 209 (02) :137-142

[8] CRYSTAL-STRUCTURE AND VIBRATIONAL-SPECTRA OF METHYL N,N-DIETHYLDITHIOCARBAMATO MERCURY(II) [J].

CHIEH, C ;

LEUNG, LPC .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1976, 54 (19) :3077-3084

[9]

FRENZ BA, 1978, COMPUTING CRYSTALLOG

[10]

GOGGIN PL, 1979, J CHEM RES-S, P2315

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