SYNTHESIS AND APPLICATION OF GRAFT POLY(VINYLIDENE POLYFLUORIDE) COPOLYMERS .1.

被引：22

作者：

BOUTEVIN, B ^{[1
]}

PIETRASANTA, Y ^{[1
]}

ROBIN, JJ ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM MONTPELLIER,CHIM APPL LAB,URA D11930,8 RUE ECOLE NORMALE,F-34053 MONTPELLIER 1,FRANCE

来源：

EUROPEAN POLYMER JOURNAL | 1991年 / 27卷 / 08期

关键词：

D O I：

10.1016/0014-3057(91)90015-G

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We studied the ozonization of poly(vinylidene fluoride) (PVDF) and compared its reactivity with those of others such as polyethylene (PE) and poly(vinyl chloride) (PVC) treated under the same conditions. We observed that PVDF is more reactive and determined the dissociation rate constant (k(d)) and activation energy (E(a)) of peroxides and hydroperoxides generated by ozonization. k(d) (5.9 . 10(-4) sec-1 at 80-degrees-C) and E(a) (37.4 kJ/mol) are similar to those found for PE and PVC.

引用

页码：815 / 820

页数：6

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