REGIOSPECIFIC AND STEREOSPECIFIC PALLADIUM-CATALYZED CYCLOADDITION OF AZETIDINES AND CARBODIIMIDES

被引：24

作者：

BAEG, JO

BENSIMON, C

ALPER, H

机构：

[1] Department of Chemistry, University of Ottawa, Ottawa, Ontario, K1N 6N5

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 01期

关键词：

D O I：

10.1021/jo00106a043

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Azetidines react with carbodiimides in the presence of bis(benzonitrile)palladium dichloride to form tetrahydropyrimidin-2-imines in 64-97% yields. The reaction is both regio- and stereospecific, the cycloaddition occurring with retention of configuration of the carbon centers bearing the substituent groups.

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页码：253 / 256

页数：4

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