SYNTHESIS OF NEW CONDURITOL ANALOGS DERIVED FROM BICYCLOOCTATRIENE - BIS-HOMO-CONDURITOL-D AND BIS-HOMO-CONDURITOL-F

被引：29

作者：

KARA, Y

BALCI, M

BOURNE, SA

WATSON, WH

机构：

[1] ATATURK UNIV,FAC SCI,DEPT CHEM,25240 ERZURUM,TURKEY

[2] TEXAS CHRISTIAN UNIV,DEPT CHEM,FT WORTH,TX 76129

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 20期

关键词：

D O I：

10.1016/S0040-4039(00)76904-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first synthesis of conduritol analogues 2 and 3 is reported. The key compound 7 reacted with KMnO4 and m-chloroperbenzoic acid in a stereospecific manner to give syn-addition products 9 and 10, respectively. Zinc-dust elimination of 10 followed by epoxide opening resulted in the formation of 3b. The free tetrol 3 was obtained by ammonolysis. The other tetrol isomer 2 was obtained by similar synthetic steps.

引用

页码：3349 / 3352

页数：4

共 10 条

[1] CONDURITOLS AND RELATED-COMPOUNDS [J].