C60H60 AND C54H48 - SILVER ION EXTRACTION WITH NEW CONCAVE HYDROCARBONS

被引:65
作者
GROSS, J
HARDER, G
VOGTLE, F
STEPHAN, H
GLOE, K
机构
[1] UNIV BONN,INST ORGAN CHEM & BIOCHEM,D-53121 BONN,GERMANY
[2] TECH UNIV DRESDEN,INST ANORGAN CHEM,O-8027 DRESDEN,GERMANY
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 04期
关键词
HOST-GUEST CHEMISTRY; HYDROCARBONS; SILVER COMPOUNDS; SPHERANDS;
D O I
10.1002/anie.199504811
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The intramolecular cavity of the spherical, concave hydrocarbons C60H60 1 and C54H48 2 is accessible to guest molecules through openings on their surfaces. The new carbocycles can be used to extract silver ions from the aqueous phase; 1 shows high selectivity and the best extraction properties of the known complex‐forming hydrocarbons. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
引用
收藏
页码:481 / 484
页数:4
相关论文
共 32 条
[1]  
Kang H.C., Hanson A.W., Eaton B., Boekelheide V., J. Am. Chem. Soc., 107, pp. 1979-1985, (1985)
[2]  
Pierre J.-L., Baret P., Chautemps P., Armand M., [2.2.2]paracyclophane, a novel type of metal cation complexing agent (.pi.-prismand), Journal of the American Chemical Society, 103, (1981)
[3]  
Cohen-Addad C., Baret P., Chautemps P., Pierre J.-L., Acta Crystallogr. Sect. C, 39, (1983)
[4]  
McMurry J.E., Harley G.J., Matz J.R., Clardy J.C., Mitchell J., J. Am. Chem. Soc., 108, (1986)
[5]  
Schmidbaur H., Bublak W., Huber B., Reber G., Muller G., Koordinationspolymere Paracyclophan-Komplexe von Kupfer und Silber, Angewandte Chemie, 98, pp. 1108-1109, (1986)
[6]  
Angew. Chem. Int. Ed. Engl., 25, (1986)
[7]  
Ikeda A., Shinkai S., J. Am. Chem. Soc., 116, (1994)
[8]  
Leppkes R., Vogtle F., Stereologe Kronenether: π-Donorbeteiligung bei der Komplexierung von Kationen?, Chemische Berichte, 116, (1983)
[9]  
Schmidbaur H., Hager R., Huber B., Muller G., Aren-Komplexe mit schwachen Wechselwirkungen: Ein makrocyclischer Tris(aren)-Komplex von Gallium(I) mit η18-Koordination, Angewandte Chemie, 99, pp. 354-356, (1987)
[10]  
Angew. Chem. Int. Ed. Engl., 26, (1987)