QUANTITATIVE RAMAN-SPECTROSCOPY OF HOMOGENEOUS MOLECULAR PROFILES IN OPTICAL WAVE-GUIDES VIA DIRECT MEASUREMENT

Quantitative measurements of Raman scattering from three-layer asymmetric slab dielectric waveguides made of organic macromolecular materials have been obtained from homogeneous distributions of scatterers as a function of mode by direct measurement of all mode-dependent quantities. For low-order modes, precision of the Raman intensity is limited to approximately 5% by uncertainty in the measurement of the coupling coefficient, gamma ; while for high-order modes, precision was limited at the same level by uncertainty in the integrated electric field due to film-thickness variations. Observation of Raman instead of Rayleigh scatter vs. distance in the waveguide allowed measurement of the optical loss function.