TEMPLATE SYNTHESIS OF A MACROCYCLIC TETRACOPPER(II) COMPLEX WITH 2 BRIDGING HYDROXIDE IONS IN FACE-TO-FACE MANNER

被引：22

作者：

SAKIYAMA, H

MOTODA, K

OKAWA, H

KIDA, S

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 07期

关键词：

D O I：

10.1246/cl.1991.1133

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 2,6-diformyl-4-methylphenol, triethylenetetramine, and copper(II) perchlorate hexahydrate in the 2:2:4 molar ratio formed a macrocyclic tetracopper(II) complex [Cu4(L)(OH)2](ClO4)4 where H2L denotes the macrocycle formed by two molecules of 2,6-diformyl-4-methylphenol and two molecules of triethylenetetramine. The two hydroxide groups, each bridging a pair of copper(II) ions, are facing each other in a close distance so as to be replaced by an azide ion, affording [Cu4(L)(N3)](ClO4)5.

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页码：1133 / 1136

页数：4

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