REDUCTIVE CYCLIZATION OF QUINONE METHIDES

被引：29

作者：

ANGLE, SR

RAINIER, JD

机构：

[1] Department of Chemistry, University of California, Riverside

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 25期

关键词：

D O I：

10.1021/jo00051a038

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first use of reduced quinone methides for the formation of carbon-carbon bonds in cyclization reactions is described. Treatment of quinone methides with SmI2 resulted in intramolecular reaction with internal activated multiple bonds to afford 5- and 6-membered carbocycles in good yields. The activated multiple bonds used are aldehydes and alpha,beta-unsaturated esters and nitriles.

引用

页码：6883 / 6890

页数：8

共 31 条

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