ALLYLBORANES - REDUCTIVE MONOALLYLATION AND TRANS-DIALLYLATION OF AROMATIC NITROGEN-CONTAINING HETEROCYCLIC-COMPOUNDS

被引：27

作者：

BUBNOV, YN

机构：

[1] N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 117913

来源：

RUSSIAN CHEMICAL BULLETIN | 1995年 / 44卷 / 07期

关键词：

ALLYLBORATION; TRIALLYLBORANE; TRIMETHALLYLBORANE; TRICROTYLBORANE; TRIPHENYLBORANE; COMPLEXES WITH PYRIDINES; PYRROLE; INDOLE; PYRIDINES; 4,4'-DIPYRIDYL; QUINOLINES; ISOQUINOLINES; PHENANTHRIDINE; REDUCTIVE MONOALLYLATION; REDUCTIVE DIALLYLATION; CIS- AND TRANS-DIALLYPYROLLIDINE; 1,2,5,6-TETRAHYDROPYRIDINES; STEREOCHEMISTRY; HYDROGENATION; 1,2-DIHYDROQUINOLINES; 1,2,3,4-TETRAHYDROISOQUINOLINES;

D O I：

10.1007/BF00700882

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reductive alpha-mono- and stereoselective trans-alpha,alpha'-diallylation of aromatic nitrogen-containing heterocycles by allylic boron derivatives have been discovered. A method for the trans-to-cis isomerization of trans-2,5-diallylpyrrolidines and trans-2,6-diallyl-1,2,5,6-tetrahydropyridines by heating with allylboranes has been developed. The above reactions unite the chemistry of nitrogen-containing heterocycles and the chemistry of organoboron compounds on a new level.

引用

页码：1156 / 1170

页数：15

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