1,3-DIPOLAR CYCLOADDITION - A NEW APPROACH TO TELECHELICS

被引:5
作者
MAIER, G [1 ]
NUYKEN, O [1 ]
LOSERT, K [1 ]
机构
[1] UNIV BAYREUTH,LEHRSTUHL MAKROMOLEK CHEMIE 1,W-8580 BAYREUTH,GERMANY
来源
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1993年 / 75卷
关键词
D O I
10.1002/masy.19930750119
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The ability of the cycloaddition reaction between aromatic aldazines and diisocyanates to form polymers was studied. Reaction conditions were found which allow the direct synthesis of telechelics by this reaction. These telechelics have two isocyanate end groups due to the nature of the cycloaddition reaction. Functionality of a telechelic oligomer was confirmed to be f = 1.95 by end goup titration. Chain extension experiments were successful with this material.
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页码:199 / 204
页数:6
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