SYNTHESIS AND REACTIVITY OF THE PENTAMETHYLCYCLOPENTADIENYL IRON ACETYL COMPLE[(ETA(5)-C(5)ME(5))FE(CO)(PPH(3))COME]

被引：17

作者：

BARRAS, JP ^{[1
]}

DAVIES, SG ^{[1
]}

METZLER, MR ^{[1
]}

EDWARDS, AJ ^{[1
]}

HUMPHREYS, VM ^{[1
]}

PROUT, K ^{[1
]}

机构：

[1] DYSON PERRINS LAB,OXFORD OX1 3QY,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 461卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83287-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[RS]-[(eta(5)-C(5)Me(5))Fe(CO)(PPh(3))COMe] (1) was synthesised from [(eta(5)-C(5)Me(5))Fe(CO)(2)](2) (3) in three steps with an overall yield of 28%. The lithium enolate from 1 was alkylated with methyl iodide and benzyl bromide to give 11 and 12 in 94 and 97% yields respectively. The corresponding diethylaluminium enolate derived from 1 reacted with high stereoselectivity with benzaldehyde whereas no selectivity was observed with the lithium enolate. A single crystal X-ray structure analysis of (RS)-[(eta(5)-C(5)Me(5))Fe(CO)(PPh(3))COCH(2)CH(2)Ph] (12) is reported.

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页码：157 / 165

页数：9

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