OXIDATION OF ISOPROPYLBENZENE BY IRON TETRAPHENYLPORPHYRIN - EVIDENCE FOR THE INTERACTION OF THE CUMYL RADICAL WITH OXYGEN DONORS

被引：23

作者：

BACIOCCHI, E ^{[1
]}

DACUNZO, F ^{[1
]}

GALLI, C ^{[1
]}

IOELE, M ^{[1
]}

机构：

[1] UNIV ROMA LA SAPIENZA,CTR CNR MECCANISMI REAZ,I-00185 ROME,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 04期

关键词：

D O I：

10.1039/c39950000429

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Evidence is presented for an unprecedented oxygen transfer from oxygen donors to a cumyl radical in the oxidation of isopropylbenzene catalysed by tetraphenyl metalloporphyrins.

引用

页码：429 / 430

页数：2

共 7 条

[1] ASMUS KD, 1988, 5TH P INT S ORG FREE, P3
[2] PERESTERS .5. DI-TERT-BUTYLPEROXYOXALATE
BARTLETT, PD
BENZING, EP
PINCOCK, RE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (07) : 1762 - 1768
[3] INCHLEY P, 1989, NEW J CHEM, V13, P69
[4] METALLOPORPHYRINS AS VERSATILE CATALYSTS FOR OXIDATION REACTIONS AND OXIDATIVE DNA CLEAVAGE
MEUNIER, B
[J]. CHEMICAL REVIEWS, 1992, 92 (06) : 1411 - 1456
[5] MINISCI F, 1990, NATO ADV SCI I A-LIF, V197, P303
[6] Ortiz de Montellano P. R., 1986, CYTOCHROME P450 STRU
[7] OXIDATION OF STYRENE DERIVATIVES BY S2O8-CU-II-O-2- IN ACETIC-ACID AND ACETONITRILE - REACTION PATHS IN OXIDATIONS VIA RADICAL CATIONS
WALLING, C
ELTALIAWI, GM
AMARNATH, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (24) : 7573 - 7578

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