CATALYTIC CONVERSIONS IN WATER - A NOVEL CARBONYLATION REACTION CATALYZED BY PALLADIUM TRISULFONATED TRIPHENYLPHOSPHINE COMPLEXES

被引：48

作者：

PAPADOGIANAKIS, G ^{[1
]}

MAAT, L ^{[1
]}

SHELDON, RA ^{[1
]}

机构：

[1] DELFT UNIV TECHNOL,ORGAN CHEM & CATALYSIS LAB,2628 BL DELFT,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 23期

关键词：

D O I：

10.1039/c39940002659

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The renewable basic chemical 5-hydroxymethylfurfural (HMF) is selectively carbonylated to the new compound 5-formylfuran-2-acetic acid using a water-soluble palladium complex of trisulfonated triphenylphosphine as the catalyst in an acidic aqueous medium at 70 degrees C and 5 bar CO pressure; when hydrogen iodide is the acid component, the reaction follows a different course and HMF is selectively reduced to 5-methylfurfural.

引用

页码：2659 / 2660

页数：2

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