GRAND-CANONICAL ENSEMBLE MONTE-CARLO SIMULATIONS OF ADSORPTION IN ENERGETICALLY HETEROGENEOUS SLIT-LIKE PORES

被引：13

作者：

KARYKOWSKI, K ^{[1
]}

RZYSKO, W ^{[1
]}

PATRYKIEJEW, A ^{[1
]}

SOKOLOWSKI, S ^{[1
]}

机构：

[1] MARIE CURIE SKLODOWSKA UNIV,FAC CHEM,DEPT CHEM PHYS,PL-20031 LUBLIN,POLAND

来源：

THIN SOLID FILMS | 1994年 / 249卷 / 02期

关键词：

D O I：

10.1016/0040-6090(94)90768-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We report the results of grand ensemble Monte Carlo simulations of argon adsorption in slit-like pores with energetically non-uniform walls. Assuming random topography of adsorbing sites we have investigated how energetic heterogeneity influences the capillary condensation. We have found that energetic heterogeneity changes the first-order capillary condensation into a continuous pore filling.

引用

页码：236 / 240

页数：5

共 23 条

[1] GRAND CANONICAL ENSEMBLE MONTE-CARLO FOR A LENNARD-JONES FLUID [J].

ADAMS, DJ .

MOLECULAR PHYSICS, 1975, 29 (01) :307-311

[2]

[Anonymous], 1982, COMPUTER SIMULATION

[3] THE DENSITY PROFILE OF A CONFINED FLUID - COMPARISON OF DENSITY FUNCTIONAL THEORY AND SIMULATION [J].

BALL, PC ;

EVANS, R .

MOLECULAR PHYSICS, 1988, 63 (01) :159-163

[4] COMPUTER-SIMULATION OF PHYSISORPTION ON A HETEROGENEOUS SURFACE [J].

BOJAN, MJ ;

STEELE, WA .

SURFACE SCIENCE, 1988, 199 (03) :L395-L402

[5] SIMULATION STUDIES OF ADSORPTION IN ROUGH-WALLED CYLINDRICAL PORES [J].

BOJAN, MJ ;

VERNOV, AV ;

STEELE, WA .

LANGMUIR, 1992, 8 (03) :901-908

[6] INFLUENCE OF SURFACE ENERGETIC HETEROGENEITY ON THE FORMATION OF ADSORBED LAYERS AND WETTING OF SOLID-SURFACES - A MONTE-CARLO STUDY [J].

CHMIEL, G ;

PATRYKIEJEW, A ;

RZYSKO, W ;

SOKOLOWSKI, S .

PHYSICAL REVIEW B, 1993, 48 (19) :14454-14462

[7] MONTE-CARLO SIMULATIONS OF ADSORPTION ON HETEROGENEOUS SURFACES WITH A RANDOM TOPOGRAPHY OF SURFACES SITES [J].

CORTES, J ;

ARAYA, P .

JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (10) :7741-7744

[8] PHASE-TRANSITIONS IN HETEROGENEOUS FILMS [J].

DASH, JG ;

PUFF, RD .

PHYSICAL REVIEW B, 1981, 24 (01) :295-309

[9] EFFECTS OF ENERGY HETEROGENEITY ON PHASE-TRANSITIONS IN A MODEL MONOLAYER SYSTEM [J].

ECKE, RE ;

DASH, JG ;

PUFF, RD .

PHYSICAL REVIEW B, 1982, 26 (03) :1288-1296

[10] THE INFLUENCE OF ADSORBENT MICROSTRUCTURE UPON ADSORPTION EQUILIBRIA - INVESTIGATIONS OF A MODEL SYSTEM [J].

KAMINSKY, RD ;

MONSON, PA .

JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (04) :2936-2948

← 1 2 3 →