REACTION OF BENZENE AND TOLUENE IN THE PRESENCE OF OXYGEN OVER H-ZSM5 ZEOLITE - AROMATIC OXYGENATES IN THE PRODUCT

被引：16

作者：

DONG, QN

ANDERSON, JR

MOLE, T

CHANG, YF

WESTERN, RJ

机构：

[1] CSIRO, DIV MAT SCI & TECHNOL, CLAYTON, VIC 3168, AUSTRALIA

[2] MONASH UNIV, DEPT CHEM, CLAYTON, VIC 3168, AUSTRALIA

来源：

APPLIED CATALYSIS | 1991年 / 72卷 / 01期

关键词：

ACIDITY; BENZENE; OXYGENATES; TOLUENE; ZEOLITES; AGING; COKE FORMATION; RESIDUE;

D O I：

10.1016/0166-9834(91)85031-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reaction residue retained by H-ZSM5 from treatment with benzene and toluene in the presence of oxygen (O2/N2 = 1/99-20/80) at 573-773 K has been studied. Retained product contained both oxygenates and hydrocarbons, the latter being similar to those obtained in the presence of oxygen, although oxygen caused some increase in anthracenes/phenanthrenes. Probable pathways for the formation of the main classes of oxygenates are discussed. The acidity of the H-ZSM5 is essential in that very little reaction occurred with silicalite.

引用

页码：99 / 107

页数：9

共 20 条

[1] RETAINED AND DESORBED PRODUCTS FROM REACTION OF 1-HEXENE OVER H-ZSM5 ZEOLITE - ROUTES TO COKE PRECURSORS [J].