SYNTHESES AND ELECTROCHEMICAL-BEHAVIOR OF NOVEL DMIT OR DMIO (DITHIOLATO) COBALT(III) COMPLEXES WITH A ETA-5-CYCLOPENTADIENYL OR ETA-5-PENTAMETHYLCYCOPENTADIENYL RING

被引：31

作者：

USHIJIMA, H ^{[1
]}

SUDOH, S ^{[1
]}

KAJITANI, M ^{[1
]}

SHIMIZU, K ^{[1
]}

AKIYAMA, T ^{[1
]}

SUGIMORI, A ^{[1
]}

机构：

[1] SOPHIA UNIV,FAC SCI & TECHNOL,DEPT CHEM,7-1 KIOI CHO,CHIYODA KU,TOKYO 102,JAPAN

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 1991年 / 5卷 / 04期

关键词：

DMIT; DMIO; METAL COMPLEXES; CYCLOPENTADIENYL; COBALT(III) COMPLEX; CYCLIC VOLTAMETRY; CONTROLLED POTENTIAL COULOMETRY; ELECTRON RESERVOIR; SULFUR-RICH ORGANIC ELECTRON DONOR;

D O I：

10.1002/aoc.590050404

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Four novel cobalt(III) complexes with a cyclopentadienyl or pentamethylcyclopentadienyl ring and dmit or dmio ligands were synthesized, and their electrochemical behaviour was investigated. All these complexes exhibited three one-electron transfer steps: one reduction and two oxidation steps. In addition, a novel organosulphur compound was afforded by electrochemical oxidation of dmit cobalt complex. Thus, these complexes may have considerable synthetic potential as precursors for electron reservoirs and organosulphur compounds.

引用

页码：221 / 228

页数：8

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