ROTATIONALLY INELASTIC-SCATTERING OF NCO((X)OVER-TILDE(2)PI)+AR - MASS EFFECTS

被引：5

作者：

LAI, LH ^{[1
]}

CHIU, YH ^{[1
]}

LIU, KP ^{[1
]}

机构：

[1] ACAD SINICA,INST ATOM & MOLEC SCI,TAIPEI 10764,TAIWAN

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 103卷 / 19期

关键词：

D O I：

10.1063/1.470159

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

State-resolved integral cross sections for the inelastic scattering of the Hund's case (a) radical NCO((X) over tilde(2)II) by Ar have been measured in a pulsed, crossed-beam apparatus. An extensive comparison has been made between its results and those for NCO+He. Substantial differences were found in nearly every aspect. It was conjectured that the observed ''mass effects'' arose mainly from the difference in interaction time which changed the dynamics from predominantly an impulsive type for NCO+He to a regime governed by multiple encounter collision for NCO+Ar. (C) 1995 American Institute of Physics.

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页码：8492 / 8500

页数：9

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