USE OF HIGH-PRESSURE TECHNIQUES FOR MEASURING REACTION-RATES IN LIQUID SOLUTIONS

被引：11

作者：

HUBBARD, CD

VANELDIK, R

机构：

[1] Department of Chemistry, University of New Hampshire, Durham

[2] Institute for Inorganic Chemistry, University of Erlangen-Nürnberg, 91056, Erlangen

来源：

INSTRUMENTATION SCIENCE & TECHNOLOGY | 1995年 / 23卷 / 01期

关键词：

D O I：

10.1080/10739149508011694

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This review describes the instrumental methods employed for measuring reaction rates in liquid solutions at elevated pressures. The current status as well as the developments leading to it are presented. The value of such measurements in elucidating reaction mechanisms is a principal focus. A wide range of examples from inorganic chemistry, organic chemistry, bioinorganic chemistry, biochemistry and organometallic chemistry which illustrates the instruments employed, general methods, and mechanistic insight, is provided.

引用

页码：1 / 41

页数：41

共 134 条

[1]

AKITT JW, 1990, NMR BASIC PRINCIPLES, V24, P189

[2] SOLVATION AND REACTIVITY OF THE LOW-SPIN TRIS-DIIMINE IRON(II) COMPLEX OF THE SCHIFF-BASE LIGAND DERIVED FROM 2-BENZOYLPYRIDINE AND 3,4-DIMETHYLANILINE, [FE(ME2BSB)3]2+ [J].