A NOVEL MODE OF REACTION OF A SUBSTITUTED ALKYL HALIDE - REDUCTION OF TRIS(TRIMETHYLSILYL)METHYL IODIDE BY METHANOL

被引：4

作者：

EABORN, C

HAPPER, DAR

机构：

[1] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND

[2] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 22期

关键词：

D O I：

10.1039/c39910001608

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tris(trimethylsilyl)methyl iodide undergoes rapid reduction to tris(trimethyl)silylmethane in methanol containing sodium methoxide or silver trifluoromethanesulfonate.

引用

页码：1608 / 1609

页数：2

共 14 条

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CHER, M
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[7] ORGANOSILICON COMPOUNDS .48. EFFECTS OF ALPHA-TRIMETHYLSILYL GROUPS ON RATES OF REACTION AT CARBON-HALOGEN BONDS
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[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 29 (03) : 389 - &
[8] STABILIZATION OF A CARBANION BY ALPHA-ME3SI GROUPS - KINETIC ACIDITY OF TRIS(TRIMETHYLSILYL)METHANE
EABORN, C
EIDENSCHINK, R
JACKSON, PM
WALTON, DRM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 101 (03) : C40 - C42
[9] ACID-BASE PROPERTIES OF FREE-RADICALS IN SOLUTION
HAYON, E
SIMIC, M
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1974, 7 (04) : 114 - 121
[10] ISAACS NS, 1987, PHYSICAL ORGANIC CHE, P269

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