A FACILE DIGERMENE-TO-GERMYLGERMYLENE REARRANGEMENT - BULKY GERMYLENE INSERTION INTO THE SI-H BOND

被引:40
作者
BAINES, KM
COOKE, JA
VITTAL, JJ
机构
关键词
D O I
10.1039/c39920001484
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The thermolysis of hexamesitylcyclotrigermane 1 in the presence of triethylsilane at 105-degrees-C yields dimesityl(triethylsilyl)germane 2 and 1,1,1,2-tetramesityl(2-triethylsilyl)digermane 3; the molecular structure of 3 has been determined by X-ray crystallography.
引用
收藏
页码:1484 / 1485
页数:2
相关论文
共 15 条
[1]   THERMOLYSIS OF CYCLOTRIGERMANE - SIMPLE PREPARATION OF DIGERMETANES CONTAINING A GERMANIUM GERMANIUM BOND [J].
ANDO, W ;
TSUMURAYA, T .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (12) :770-772
[2]   MOLECULAR-STRUCTURES OF A SILADIGERMIRANE AND A CYCLOTRIGERMANE [J].
BAINES, KM ;
COOKE, JA ;
PAYNE, NC ;
VITTAL, JJ .
ORGANOMETALLICS, 1992, 11 (03) :1408-1411
[3]   THERMOLYSIS OF A SILADIGERMIRANE - EVIDENCE FOR THE FORMATION OF A GERMASILENE [J].
BAINES, KM ;
COOKE, JA .
ORGANOMETALLICS, 1991, 10 (10) :3419-3421
[4]  
Cameron T. S., 1975, CRYST STRUCT COMMUN, V4, P601
[5]   PYROLYSIS OF SILYLPHOSPHINE AND GERMYLSILANE AND FORMATION OF PHOSPHYLENE (PH) [J].
ELLIOTT, LE ;
ESTACIO, P ;
RING, MA .
INORGANIC CHEMISTRY, 1973, 12 (09) :2193-2194
[6]   GERMANIUM ATOMS . REACTIONS WITH GERMANE AND SILANE [J].
GASPAR, PP ;
LEVY, CA ;
FROST, JJ ;
BOCK, SA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (06) :1573-&
[7]  
Glockling F., 1969, CHEM GERMANIUM
[8]   DIMETHYLGERMYLENE INSERTION INTO THE SI-H BOND [J].
MOCHIDA, K ;
HASEGAWA, A .
CHEMISTRY LETTERS, 1989, (06) :1087-1088
[9]   CONCERNING THE SILICON-GERMANIUM BOND - THE STRUCTURES OF ISOMERIC PH3GE-SIME3,PH3SI-GEME3 [J].
PANNELL, KH ;
KAPOOR, RN ;
RAPTIS, R ;
PARKANYI, L ;
FULOP, V .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 384 (1-2) :41-47
[10]   ORGANOMETALLOIDAL DERIVATIVES OF THE TRANSITION-METALS .11. SYNTHESIS AND CRYSTAL-STRUCTURES OF PH3GESME3 AND PH3GESIME2FE(CO)2(ETA-5-C5H5) [J].
PARKANYI, L ;
HERNANDEZ, C ;
PANNELL, KH .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 301 (02) :145-151