PREPARATIONS OF BICYCLICLACTOLS FROM ALLYL AND OR HOMOALLYL PROPARGYL ACETAL-COBALT COMPLEXES AND ITS APPLICATION TO THE FORMAL SYNTHESIS OF (+/-) LOGANINE

被引：43

作者：

JEONG, N

LEE, BY

LEE, SM

CHUNG, YK

LEE, SG

机构：

[1] SEOUL NATL UNIV,DEPT CHEM,SEOUL 151,SOUTH KOREA

[2] KOREA RES INST CHEM TECHNOL,TAEJON,SOUTH KOREA

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 25期

关键词：

D O I：

10.1016/S0040-4039(00)60606-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3-oxa-2-alkoxy bicyclo [3,3,0]-oct-5-en-7-ones and 3-oxa-2-alkoxy bicyclo [4,3,0]-non-5-en-7-ones were efficiently prepared from the corresponding bis(allyl or homoallyl)propargyl acetal-cobalt complexes in the presence of trimethylamine N-oxide. This methodology was successfully applied to the formal synthesis of (+/-) loganine.

引用

页码：4023 / 4026

页数：4

共 26 条

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